CAS# 6295-58-5 CAS NO.6295-58-5

Ozonolysis of alkenes and study of reactions of polyfunctional compounds Ozonolysis of alkenes and study of reactions of polyfunctional compounds…

Ozonolysis of alkenes and study of reactions of polyfunctional compounds Ozonolysis of alkenes and study of reactions of polyfunctional compounds. X. Peroxide products of the ozonolysis of derivatives of stereoisomeric bicyclo[2.2.1]hept-5-en-2,3-di- and -2-carboxylic acids. Odinokov, V. N.; Kukovinets, O. S.; Tolstikov, G. A. (Inst.In this article, certain chemicals are used. One of their cas registry numbers is 129-64-6 Khim., Ufa, USSR). Zh. 6295-58-5 is also in the experiment. Org. Khim., 13(11), 2342-53 (Russian) 1977. CODEN: ZORKAE. ISSN: 0514-7492. DOCUMENT TYPE: Journal CA Section: 24 (Alicyclic Compounds) The peroxide products of ozonolysis of I, I acid, II, III, IV and V were sepd. and characterized. The hydroperoxide group in substituted cyclopentane rings interacted intramolecularly with aldehyde groups, giving dioxaheptane rings. Free carboxy groups or anhydride rings might be involved in ring-chain transformations with formation of a 5 membered lactone ring, that led to isomerization of the aldehyde group in the cis position to a carboxy group. Under the influence of tertiary amines the hydroperoxide group isomerized to a carboxylate that led to formation of aldehydocarboxylic acid. ..